Electronic Configuration of High-Spin Imidazole-Ligated Iron(II) Octaethylporphyrinates
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چکیده
منابع مشابه
Simple dimer containing dissociatively stable mono-imidazole ligated ferrohemes.
In weakly coordinating solvents FeII meso-(N-methylimidazol-2-yl)porphine Fe exists as a stable dimer (Kd=50+/-30 nM) that binds ligands without undergoing dissociation and is presently the simplest complex in which the mono-imidazole ligation of a ferroheme is enforced without excess imidazole in solution.
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ژورنال
عنوان ژورنال: Inorganic Chemistry
سال: 2006
ISSN: 0020-1669,1520-510X
DOI: 10.1021/ic052194v